Facile Oxygen Atom Insertion into Unactivated C(sp<sup>3</sup>)–C(sp<sup>2</sup>) Single Bonds in Reactions of Iridium(III) Complexes with O<sub>2</sub>
收藏NIAID Data Ecosystem2026-03-09 收录
数据链接：
官方服务：
资源简介：
The Ir(III) pyridylidene TpMe2Ir(CH2CH2-o-C6H4)(CN(H)CHCHCHCH) (3; TpMe2 = hydrotris(3,5-dimethylpyrazolyl)borate) reacts with oxygen (air), under mild conditions, to afford a bicyclic ether-semiaminal species. The new structure derives formally from two oxidative events. One is dehydrogenative in nature (loss of 2H), and the other consists of the insertion of an oxygen atom into a nonactivated benzylic C–C bond. The reaction has been extended to a related iridacycle that contains a pyrazole coligand instead of the pyridylidene.
创建时间：
2016-02-20
