Unprecedented Reduction of 2,2′-Bipyrimidine in a One-Pot Synthesis of Neutral Rhenium(I)-Based Molecular Rectangles
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https://figshare.com/articles/dataset/Unprecedented_Reduction_of_2_2_Bipyrimidine_in_a_One_Pot_Synthesis_of_Neutral_Rhenium_I_Based_Molecular_Rectangles/2939788
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资源简介：
An unprecedented partial reduction of 2,2′-bipyrimidine (bpym) occurred, affording the H6bpym2− moiety, during the one-pot self-assembly of neutral Re(I)-based molecular rectangles and bimetallic products under solvothermal conditions. Their structures were unambiguously characterized by 1H NMR and single-crystal X-ray diffraction analyses, and their electrochemical, electronic absorption, and photoluminescent properties were studied. The reaction pathway was also investigated.
创建时间：
2016-02-27
