σ-Alane Complexes of Chromium, Tungsten, and Manganese
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https://figshare.com/articles/dataset/_Alane_Complexes_of_Chromium_Tungsten_and_Manganese/2551825
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资源简介：
Photolytic ligand displacement and salt metathesis routes
have
been exploited to give access to κ1 σ-alane
complexes featuring Al–H bonds bound to [W(CO)5]
and [Cp′Mn(CO)2] fragments, together with a related
κ2 complex of [Cr(CO)4]. Spectroscopic,
crystallographic, and quantum chemical studies are consistent with
the alane ligands acting predominantly as σ-donors, with the
resulting binding energies calculated to be marginally greater than
those found for related dihydrogen complexes.
创建时间：
2016-02-22
