Materials Data on Ag3O4 by Materials Project

Ag3O4 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. there are two inequivalent Ag+2.67+ sites. In the first Ag+2.67+ site, Ag+2.67+ is bonded in a rectangular see-saw-like geometry to four O2- atoms. There are one shorter (2.07 Å) and three longer (2.09 Å) Ag–O bond lengths. In the second Ag+2.67+ site, Ag+2.67+ is bonded in a distorted square co-planar geometry to four O2- atoms. There are two shorter (2.07 Å) and two longer (2.09 Å) Ag–O bond lengths. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted trigonal non-coplanar geometry to three Ag+2.67+ atoms. In the second O2- site, O2- is bonded in a trigonal non-coplanar geometry to three Ag+2.67+ atoms.