Access to Polyfunctionalized Chiral Piperidines through Enantioselective Addition–Carbocyclization Cascade Reaction Catalyzed by a Rhodium(I)–Diene Complex
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https://figshare.com/articles/dataset/Access_to_Polyfunctionalized_Chiral_Piperidines_through_Enantioselective_Addition_Carbocyclization_Cascade_Reaction_Catalyzed_by_a_Rhodium_I_Diene_Complex/2112592
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资源简介:
A new addition–carbocyclization
cascade reaction initiated
by arylboronic acids and catalyzed by a rhodium/chiral diene complex
is described. Starting from N-bridged oxoenoate derivatives,
highly functionalized piperidines bearing three contiguous stereogenic
centers were obtained with excellent enantio- and diastereoselectivities.
创建时间:
2016-02-12



