Visible-Light-Induced Photocatalytic Synthesis of β‑Keto Dithiocarbamates via Difunctionalization of Styrenes
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https://figshare.com/articles/dataset/Visible-Light-Induced_Photocatalytic_Synthesis_of_Keto_Dithiocarbamates_via_Difunctionalization_of_Styrenes/14593637
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A facile photocatalyzed strategy for difunctionalization of styrenes in the presence of CS2 and amines providing β-keto dithiocarbamates has been developed. In the case of 4-nitrostyrene and 2-vinylpyridine, however, only 2-arylethylthiocarbamates are interestingly formed without the aid of photoredox catalysis/TBHP.
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2021-05-14



