Gold Catalysis: Regio- and Stereoselective Total Synthesis of Xyloketals D and G and the Related Natural Product Alboatrin
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下载链接：
https://figshare.com/articles/dataset/Gold_Catalysis_Regio_and_Stereoselective_Total_Synthesis_of_Xyloketals_D_and_G_and_the_Related_Natural_Product_Alboatrin/2433673
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资源简介：
A new
and efficient one-pot desilylation–gold-catalyzed
cycloisomerization of alkynes containing a silyl-protected phenolic
−OH and a free alcoholic −OH unit leads selectively
to the formation of tetrahydrofuranobenzopyran ring system. This approach
has been used for the regio- and stereoselective synthesis of xyloketal
D, xyloketal G, and the related natural product alboatrin.
创建时间：
2016-02-19
