Chameleon Behavior of a Newly Synthesized Scandium Nitrilimine Derivative
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The synthesis, structural characterization, and reactivity of the first example of a scandium -substituted nitrilimine are presented. This unique complex exhibits high thermal stability but shows a rich reactivity toward a variety of unsaturated substrates, including aldehyde, ketone, nitrile, and allene derivatives. The versatility of the complex was further highlighted by density functional theory mechanistic studies.
创建时间：
2016-02-19
