Two Unprecedented Three-Dimensional PbII Polymorphs and Structural Diversities Built on a Kinked Flexible Dicarboxylate Building Block
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Two unprecedented three-dimensional (3D) true coordination polymorphs, namely, [Pb2(phda)2(H2O)]n·2nH2O (1a, and 1b) (H2phda = 1,4-phenylenediacetate acid), which show distinct novel topological networks, have been successfully prepared by utilizing a kinked flexible H2phda. This work shows the first example of two different isomers reported for a flexible ligand acting as a bridge.
创建时间：
2016-02-23
