Reactivity of a Tin(II) (Iminophosphinoyl)(thiophosphinoyl)methanediide Complex toward Isocyanates and Rhodium(I) Chloride

Figshare2016-02-20 更新2026-04-29 收录

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The reaction of the tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide [(PPh2NSiMe3)(PPh2S)CSn:]2 (1) with AdNCO (Ad = adamantyl), ArNCO (Ar = 2,6-Pri2C6H3), and [RhCl(cod)]2 in THF afforded [(PPh2NSiMe3)(PPh2S)C{C(O)N(Ad)}Sn:] (2), [(PPh2NSiMe3)(PPh2S)C¯{C(O)N(Ar)}Sn+:] (3), and [(PPh2NSiMe3)(PPh2S)C{Rh(cod)}(SnCl)] (4), respectively. Compounds 2–4 have been characterized by NMR spectroscopy and X-ray crystallography.

创建时间：

2016-02-20