Cp*Rh(III)-Catalyzed Regioselective C(sp3)–H Electrophilic Trifluoromethylthiolation of 8‑Methylquinolines
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资源简介：
Rh(III)-catalyzed regioselective trifluoromethylthiolation of the unactivated C(sp3)–H bond of 8-methylquinolines with bench-stable electrophilic trifluoromethylthiolating reagent via C(sp3)–H activation is explored. Various substituted 8-methylquinolines provided the products in good yields with high regioselectivity. Current reaction conditions are also applicable for the late-stage functionalization of natural molecule santonin and caffeine-substituted 8-methylquinoline.
创建时间：
2021-09-23
