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Tetracoordinate Imidazole-Based Boron Complexes for the Selective Detection of Picric Acid

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Figshare2016-11-01 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Tetracoordinate_Imidazole-Based_Boron_Complexes_for_the_Selective_Detection_of_Picric_Acid/4004763
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N,N-Dimethylamine and N,N-diphenylamine-decorated highly fluorescent imidazole borates have been synthesized and investigated as new fluorophores for the selective detection of trinitrophenol/picric acid (PA). Structural studies of a probe 1 and PA (1·PA) complex revealed that the adduct formed by the deprotonation of PA by the −NMe2 group along with weak interactions is responsible for the selective detection of PA over other polynitrated organic compounds.
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2016-11-01
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