Tetracoordinate Imidazole-Based Boron Complexes for the Selective Detection of Picric Acid
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N,N-Dimethylamine and N,N-diphenylamine-decorated highly fluorescent imidazole borates have been synthesized and investigated as new fluorophores for the selective detection of trinitrophenol/picric acid (PA). Structural studies of a probe 1 and PA (1·PA) complex revealed that the adduct formed by the deprotonation of PA by the −NMe2 group along with weak interactions is responsible for the selective detection of PA over other polynitrated organic compounds.
创建时间:
2016-11-01



