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Solvent-Controlled, Tunable Hydrosulfonylation of 3‑Cyclopropylideneprop-2-en-1-ones

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Figshare2016-08-29 更新2026-04-29 收录
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An interesting and tunable hydrosulfonylation of 3-cyclo­propylidene­prop-2-en-1-ones with sodium sulfinates and acetic acid is described. The corresponding β- or γ-addition products can be produced in good to excellent yields with high selectivities, respectively. A rationale for these transformations is proposed base on the controlled experiments.

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2016-08-29
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