Efficient Carbene and Carbyne Formation in Molybdenum(0) and Tungsten(0) Dinitrogen Complexes
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下载链接:
https://figshare.com/articles/dataset/Efficient_Carbene_and_Carbyne_Formation_in_Molybdenum_0_and_Tungsten_0_Dinitrogen_Complexes/2316442
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资源简介:
Zerovalent group
6 dinitrogen phosphine complexes react with 3,3-diphenylcyclopropene
to give vinylcarbyne hydride complexes that have been characterized
crystallographically. Computational studies indicate that the observed
products resulted from the α-migration and rearrangement of
an initially formed vinylcarbene.
创建时间:
2014-03-10



