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Efficient Carbene and Carbyne Formation in Molybdenum(0) and Tungsten(0) Dinitrogen Complexes

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NIAID Data Ecosystem2026-03-08 收录
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Zerovalent group 6 dinitrogen phosphine complexes react with 3,3-diphenylcyclopropene to give vinylcarbyne hydride complexes that have been characterized crystallographically. Computational studies indicate that the observed products resulted from the α-migration and rearrangement of an initially formed vinylcarbene.

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2014-03-10
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