Enantioselective Cycloisomerization of 1,6-Enynes to Bicyclo[3.1.0]hexanes Catalyzed by Rhodium and Benzoic Acid
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https://figshare.com/articles/dataset/Enantioselective_Cycloisomerization_of_1_6_Enynes_to_Bicyclo_3_1_0_hexanes_Catalyzed_by_Rhodium_and_Benzoic_Acid/2288224
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资源简介：
It has been established
that a cationic Rh(I)/(S)-Segphos or (S)-DTBM-Segphos complex and benzoic
acid catalyze the enantioselective cycloisomerization of 1,6-enynes,
possessing carbonyl groups at the enyne linkage, to 2-alkylidenebicyclo[3.1.0]hexanes.
The present cycloisomerization may involve site selective γ-hydrogen
elimination. The one-pot enantioselective cycloisomerization and lactonization
of 1,6-enynes, leading to bicyclic lactones, has also been accomplished.
创建时间：
2014-05-28
