Dataset from the analysis of the dielectric and calorimetric response of anisotropic sizable glass-forming isomers differing in the position of the –CF3 group attached to the phenyl ring.

This dataset contains dielectric and calorimetric data published in the article entitled “The influence of molecular shape on reorientation dynamics of sizable glass-forming isomers at ambient and elevated pressure” (DOI). The raw data provided contain results collected for three glass-forming isomers (referred to as meta-CF3, ortho-CF3, para-CF3) having the same non-polar sizable core, composed of diphenylamine, fluorene, and alkyl chains, connected to a phenyl ring substituted variously with -CF3 group. These data correspond to Figures 2-11 published in the article (https://link). Raw data were generated during measurements using (1) broadband dielectric spectroscopy (BDS) over a wide range of temperatures and pressures (BDS), (2) differential scanning calorimetry (DSC), and (3) temperature-modulated differential scanning calorimetry (TMDSC).