Tetrahedral-Shaped Anions as a Template in the Synthesis of High-Nuclearity Silver(I) Dithiophosphate Clusters
收藏NIAID Data Ecosystem2026-03-07 收录
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Novel Ag32 clusters, [Ag16(EO4){S2P(OEt)2}12]2 (PF6)4 (E = S, 1; Se, 2) and [Ag16(MO4){S2P(OEt)2}12]2(PF6)4 (M = Cr, 3; Mo, 4), were prepared in situ from the addition of a tetrahedral-shaped anion as a template to the pentanuclear extended chain [Ag5{S2P(OEt)2}4]n(PF6)n.
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2016-02-23
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