Reduction of CO2 into Methylene Coupled with the Formation of C–S Bonds under NaBH4/I2 System
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A selective four-electron reduction of CO2 with thiophenol using NaBH4 as a reductant is described to access dithioacetals. This reaction provides a novel synthetic method for the highly selective conversion of CO2 into methylene, and a new access to molecular structures via formation of C–S bonds using CO2 as the C1 source.
创建时间：
2018-10-11
