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Two-Step Asymmetric Reaction Using the Frozen Chirality Generated by Spontaneous Crystallization

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NIAID Data Ecosystem2026-03-07 收录
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https://figshare.com/articles/dataset/Two_Step_Asymmetric_Reaction_Using_the_Frozen_Chirality_Generated_by_Spontaneous_Crystallization/2521828
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资源简介:
N,N-Diallyl-4-methyl-1-propyl-2-quinolone-3-carboxamide afforded chiral crystals of a P21 crystal system by spontaneous crystallization. The molecular chirality in the crystal was retained after the crystals were dissolved in a solvent at a low temperature, and the frozen molecular chirality was effectively transferred to the products by a two-step reaction involving hydrogenation and intermolecular photocycloaddition reactions.
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2016-02-20
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