Sequential Functionalization of meta-C–H and ipso-C–O Bonds of Phenols
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https://figshare.com/articles/dataset/Sequential_Functionalization_of_i_meta_i_-C_H_and_i_ipso_i_-C_O_Bonds_of_Phenols/7624082
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The use of a template as a linchpin motif in directed remote C–H functionalization is a versatile yet relatively underexplored strategy. We have developed a template-directed approach to realizing one-pot sequential palladium-catalyzed meta-selective C–H olefination of phenols, and nickel-catalyzed ipso-C–O activation and arylation. Thus, this bifunctional template converts phenols to synthetically useful 1,3-disubstituted arenes.
创建时间：
2019-01-24
