Synthesis of a Neo-Confused Octaphyrin and the Formation of Its Mononuclear Complexes
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https://figshare.com/articles/dataset/Synthesis_of_a_Neo_Confused_Octaphyrin_and_the_Formation_of_Its_Mononuclear_Complexes/2126419
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资源简介：
Novel neo-confused octaphyrin(1.1.1.1.1.1.1.0)
(1)
was synthesized by oxidative ring closure of an octapyrrane bearing
two terminal “confused” pyrroles. Crystal structures
of its Zn(II) and Cu(II) complexes (2 and 3) show a figure-of-eight conformation with unique mononuclear coordination
structures. Photophysical data and theoretical calculations suggest
that the neo-confused octaphyrin 1 is a 34π electron
conjugated species showing nonaromaticity. Coordination of copper
and zinc ions results in the further narrowing of the HOMO–LUMO
gaps.
创建时间：
2016-02-13
