Chiral Induction in the Ionothermal Synthesis of a 3D Chiral Heterometallic Metal–Organic Framework Constructed from Achiral 1,4-Naphthalenedicarboxylate
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A chiral heteometallic compound, [(EMIM)NaCu(1,4-ndc)2]n (1), constructed from the achiral 1,4-naphthalenedicarboxylate (1,4-ndc) ligand has been ionothermally synthesized and structurally and magnetically characterized. The chiral induction effect of the enantiopure 1-ethyl-3-methylimidazolium (EMIM) l-lactate additive in the ionothermal reaction is briefly discussed.
创建时间:
2013-06-17



