Trigonal Bipyramidal Dy5 Cluster Exhibiting Slow Magnetic Relaxation
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A pentanuclear dysprosium cluster, [Dy5(μ3–OH)6(Acc)6(H2O)10]·Cl9·24H2O (1), has been synthesized through the reaction of 1-amino-cyclohexanel-carboxylic acid (Acc) and DyCl3·5H2O. Crystal structural analysis reveals that the metal core of cluster 1 shows an unprecedented trigonal bipyramidal (TBP) geometry. Magnetic studies indicate that the Dy5 cluster exhibits slow magnetic relaxation.
创建时间:
2016-02-22



