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Increased Activity of in Situ Catalysts for Alkyne Metathesis

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https://figshare.com/articles/dataset/Increased_Activity_of_in_Situ_Catalysts_for_Alkyne_Metathesis/3743076
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Reaction of an enyne (1,1-diphenyl-pent-1-ene-3-yne) with a preheated mixture of Mo(CO)6/4-chlorophenol/3-hexyne at 130 °C furnished 1,1,6,6-tetraphenylhex-1,5-diene-3-yne in an 80% yield. If the starting material was heated with a mixture of Mo(CO)6 and 4-chlorophenol under identical conditions, no reaction was observed.
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2016-08-20
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