Trifluoromethanesulfonyl Hypervalent Iodonium Ylide for Copper-Catalyzed Trifluoromethylthiolation of Enamines, Indoles, and β‑Keto Esters
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下载链接：
https://figshare.com/articles/dataset/Trifluoromethanesulfonyl_Hypervalent_Iodonium_Ylide_for_Copper_Catalyzed_Trifluoromethylthiolation_of_Enamines_Indoles_and_Keto_Esters/2404009
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资源简介：
A novel electrophilic-type
trifluoromethylthiolation reagent, a
trifluoromethanesulfonyl hypervalent iodonium ylide, was designed
and reacted well with various nucleophiles to afford the desired CF3S-substituted products. In situ reduction of the trifluoromethanesulfonyl
group to give the trifluoromethylthio group, which is the key step
in this process, was realized in the presence of copper(I) chloride.
创建时间：
2013-06-19
