The Total Synthesis of Hyperfirin via a Cyclooctadiene Strategy
收藏NIAID Data Ecosystem2026-05-02 收录
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https://figshare.com/articles/dataset/The_Total_Synthesis_of_Hyperfirin_via_a_Cyclooctadiene_Strategy/26280620
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资源简介：
Polycyclic polyprenylated
acylphloroglucinols (PPAPs)
combine compelling
structural complexity with effective biological activity. The total
synthesis of Hyperfirin is reported as one linear sequence. Key to
this novel modular strategy is to access the bicyclo[3.3.1]nonane-2,4,9-trione
framework via transannular acylation of a decorated eight-membered
ring, followed by late stage bridgehead substitution. The described
route adds flexibility to PPAP construction and broadens the scope
of eight-membered ring chemistry.
创建时间：
2024-07-12
