Dinitrogen Reduction via Photochemical Activation of Heteroleptic Tris(cyclopentadienyl) Rare-Earth Complexes
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https://figshare.com/articles/dataset/Dinitrogen_Reduction_via_Photochemical_Activation_of_Heteroleptic_Tris_cyclopentadienyl_Rare_Earth_Complexes/2435158
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资源简介：
Dinitrogen
can be reduced by photochemical activation of the Ln3+ mixed-ligand
tris(cyclopentadienyl) rare-earth complexes
(η5-C5Me5)3–x(C5Me4H)xLn (Ln = Y, Lu, Dy; x = 1, 2). [(C5Me4R)2Ln]2(μ-η2:η2-N2) products (R = H, Me) are formed
in reactions in which N2 is reduced to (NN)2– and (C5Me4H)− is oxidized to (C5Me4H)2. Density
functional theory indicates that this unusual example of rare-earth
photochemistry can be rationalized by absorptions involving the (η3-C5Me4H)− ligands.
创建时间：
2016-02-19
