Palladium–Osmium Heterometallic Clusters Containing N‑Heterocyclic Carbene Ligands
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https://figshare.com/articles/dataset/Palladium_Osmium_Heterometallic_Clusters_Containing_N_Heterocyclic_Carbene_Ligands/2339401
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资源简介：
The
room-temperature reaction of [Os3(CO)12] with
[PdCl(allyl)(NHC)], where NHC (N-heterocyclic carbene) = SIPr
[N,N′-bis(2,6-diisopropylphenyl)imidazolidin-2-ylidene]
or IPr [N,N′-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene],
afforded Pd–Os mixed metal clusters with formulas of [PdnOs3(CO)12(NHC)n] (n = 1–3). These
are the first examples of Pd–Os heterometallic clusters containing
NHC ligands, and they have all been structurally characterized. In
all these clusters, the metal cores are raftlike, with carbonyl ligands
bridging all the Os–Pd edges.
创建时间：
2016-02-18
