Highly Stereoselective C–C Bond Formation by Rhodium-Catalyzed Tandem Ylide Formation/[2,3]-Sigmatropic Rearrangement between Donor/Acceptor Carbenoids and Chiral Allylic Alcohols
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https://figshare.com/articles/dataset/Highly_Stereoselective_C_C_Bond_Formation_by_Rhodium_Catalyzed_Tandem_Ylide_Formation_2_3_Sigmatropic_Rearrangement_between_Donor_Acceptor_Carbenoids_and_Chiral_Allylic_Alcohols/2508367
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资源简介：
The tandem ylide formation/[2,3]-sigmatropic rearrangement
between
donor/acceptor rhodium carbenoids and chiral allyl alcohols is a convergent
C–C bond forming process, which generates two vicinal stereogenic
centers. Any of the four possible stereoisomers can be selectively
synthesized by appropriate combination of the chiral catalyst Rh2(DOSP)4 and the chiral alcohol.
创建时间：
2012-07-04
