Syntheses, structures, photoluminescence, and near-infrared of pentanuclear Tb(III), Yb(III) dibenzoylmethane complexes
收藏Taylor & Francis Group2020-11-20 更新2026-04-16 收录
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https://tandf.figshare.com/articles/dataset/Syntheses_structures_photoluminescence_and_near-infrared_of_pentanuclear_Tb_III_Yb_III_dibenzoylmethane_complexes/12366662
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资源简介：
Two pentanuclear terbium and ytterbium hydroxy cluster of composition Ln<sub>5</sub>(μ<sub>4</sub>-OH)(μ<sub>3</sub>-OH)<sub>4</sub>(μ-η<sup>2</sup>-Ph<sub>2</sub>acac)<sub>4</sub>(η<sup>2</sup>-DBM)<sub>6</sub> were prepared starting from LnCl<sub>3</sub>·6H<sub>2</sub>O and dibenzoylmethane [Ln = Tb (<b>1)</b>, Yb (<b>2</b>), DBM = dibenzoylmethane]. X-ray crystallographic analysis reveals that complexes <b>1</b> and <b>2</b> crystallize in the tetragonal space group <i>P</i>4/<i>n</i>, and the lanthanide atoms adopt the expected square-based pyramidal arrangement. Property investigation indicates that complexes <b>1</b> and <b>2</b> display characteristics of luminescence of Tb(III) and near-infrared of Yb(III).
提供机构：
Xiqiang Tian; Yanping Dong
创建时间：
2020-05-25
