Retention of Pt→B Bonding in Oxidative Addition Reactions of the Platinaboratrane [Pt(PPh<sub>3</sub>){B(mt)<sub>3</sub>}]<i>(Pt→B)<sup>10</sup></i> (mt = Methimazolyl)
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The platinaboratrane [Pt(PPh3){B(mt)3}](Pt→B)10 (mt = methimazolyl) is prone to oxidative addition reactions with a range of substrates (Cl2, Br2, I2, HCl, CH3I) without disrupting the platinum−boron dative bond, as illustrated by the first structurally characterized platinaboratranes [PtH(PPh3){B(mt)3}]Cl(Pt→B)8 and [PtI2{B(mt)3}](Pt→B)8.
创建时间：
2008-02-11
