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The First Limonoid Peroxide in the Meliaceae Family: Walsuronoid A from <i>Walsura robusta</i>

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https://figshare.com/articles/dataset/The_First_Limonoid_Peroxide_in_the_Meliaceae_Family_Walsuronoid_A_from_i_Walsura_robusta_i_/12066699
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资源简介:
Walsuronoid A (1), a limonoid featuring an unprecedented 3,4-peroxide-bridged A-seco skeleton, together with walsuronoids B (2) and C (3) possessing a rare 18(13→14)-abeo-limonoid skeleton, was isolated from Walsura robusta. The structures were elucidated by spectroscopic analysis and chemical correlation, and that of 1 was confirmed by single-crystal X-ray diffraction. Biosynthetic pathway of 2 and 3 was proposed and was chemically mimicked. Compounds 1 and 2 showed weak antimalarial activity.
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2007-06-07

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