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Noncyclic [10-<i>S</i>-5] Sulfuranide Dioxide Salts with Three S−C Bonds: A New Class of Stable Hypervalent Compounds

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NIAID Data Ecosystem2026-03-06 收录
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Phenyl triflate reacts with CF3SiMe3/Q+F- (Q+ = [K(18-crown-6)]+, Me4N+) and (Me2N)3S+Me3SiF2- to afford the first noncyclic [10-S-5] sulfuranide dioxide salts, [(CF3)3SO2]-Q+, with three S−C bonds, whose molecular structure was determined by X-ray crystallography.

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2016-08-18
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