Formation of an Iodide-Bridged Diruthenium Complex from [(η<sup>5</sup>-Ph<sub>4</sub>C<sub>4</sub>COH)(CO)<sub>2</sub>RuI] and [(Ph<sub>4</sub>C<sub>4</sub>CO)(CO)<sub>2</sub>Ru]<sub>2</sub>: An Efficient Catalyst for Alcohol Oxidation with Ag<sub>2</sub>O
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Iodide-bridged diruthenium complexes, [(η5-2,5-R2-3,4-Ph2C4COH)(CO)2Ru−(μ-I)−Ru(CO)2(η4-2,5-R2-3,4-Ph2C4CO)] (6a, R = Ph; 6b, R = Me), were formed from the reaction of (η5-2,5-R2-3,4-Ph2C4COH)(CO)2RuI (2c, R = Ph; 2d, R = Me) with [(2,5-R2-3,4-Ph2C4CO)(CO)2Ru]2 (7a, R = Ph; 7b, R = Me). The complexes exhibited a high catalytic activity for the oxidation of alcohols with silver oxide at room temperature.
创建时间：
2009-08-10
