Dinitrogen Splitting and Functionalization in the Coordination Sphere of Rhenium
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资源简介：
[ReCl3(PPh3)2(NCMe)] reacts with pincer ligand HN(CH2CH2PtBu2)2 (HPNP) to five coordinate rhenium(III) complex [ReCl2(PNP)]. This compound cleaves N2 upon reduction to give rhenium(V) nitride [Re(N)Cl(PNP)], as the first example in the coordination sphere of Re. Functionalization of the nitride ligand derived from N2 is demonstrated by selective C–N bond formation with MeOTf.
创建时间：
2016-02-17
