Branch-Selective, Iridium-Catalyzed Hydroarylation of Monosubstituted Alkenes via a Cooperative Destabilization Strategy
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https://figshare.com/articles/dataset/Branch_Selective_Iridium_Catalyzed_Hydroarylation_of_Monosubstituted_Alkenes_via_a_Cooperative_Destabilization_Strategy/2036931
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Highly branch-selective, carbonyl-directed hydroarylations of monosubstituted alkenes are described. The chemistry relies upon a cationic Ir(I) catalyst modified with an electron deficient, wide bite angle bisphosphine ligand. This work provides a regioisomeric alternative to the Murai hydroarylation protocol.
创建时间:
2015-12-17



