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Halonium Ion Triggered Rearrangement of Unsaturated Benzo-Annulated Bi- and Tricyclic Sulfonamides

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NIAID Data Ecosystem2026-03-09 收录
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https://figshare.com/articles/dataset/Halonium_Ion_Triggered_Rearrangement_of_Unsaturated_Benzo_Annulated_Bi_and_Tricyclic_Sulfonamides/2365162
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资源简介:
The halonium ion mediated 1,2-Wagner–Meerwein-type rearrangement of a series of benzo-fused bi- and tricyclic sulfonamides is reported. During this rearrangement the carbon–carbon bond that migrates was selectively set in the intramolecular Mizoroki–Heck (IHR) synthesis of the starting materials. Consequently, this method constitutes a means to access the regioisomeric series of cyclic sulfonamides not observed during the Mizoroki–Heck reaction.
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2016-02-18
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