Dataset of Malonate Enol Ether Synthesis by Additions of Diester Metal Carbenes to Ketones and Subsequent Dual Orthogonal Reactivity
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https://yareta.unige.ch/archives/524425cc-fd02-4f33-b544-e9335a7e6fbb
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资源简介：
Effective formation of malonate enol ethers by reaction of cyclic ketones with α diazomalonates is reported using [CpRu(CH3CN)3][BArF] as catalyst. The 2 vinyloxymalonate adducts are amenable to comprehensive and orthogonal functionalizations on either malonate and enol moieties; further synergistic reactivity opens the stage to varied annulation strategies.
提供机构：
Université de Genève, Yareta
创建时间：
2021-02-01
