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Decorated BODIPY Fluorophores and Thiol-Reactive Fluorescence Probes by an Aldol Addition

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https://figshare.com/articles/dataset/Decorated_BODIPY_Fluorophores_and_Thiol-Reactive_Fluorescence_Probes_by_an_Aldol_Addition/4831744
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资源简介:
A novel entry to meso-decorated BODIPY motifs on the basis of an unusual aldol-type addition with diethyl ketomalonate is reported. The evolving β-hydroxyl group can be optionally eliminated, which suppresses the fluorescence of the BODIPY core by attachment of a π-electronically coupled methylidene malonate unit. This unit serves as a versatile, highly electrophilic acceptor platform for various nucleophilic additions. Corresponding products benefit from a fully restored fluorescence.
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2017-04-07
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