Pd-Catalyzed Tandem C–H Azidation and N–N Bond Formation of Arylpyridines: A Direct Approach to Pyrido[1,2‑b]indazoles

A novel Pd-catalyzed nitrogenation of arylpyridines via C–H azidation has been developed. Direct C–N and N–N formations are achieved for this N-atom incorporation transformation using azides as the N-atom source. This method provides an alternatively concise approach for the construction of bioactively important pyrido[1,2-b]indazoles.