Thiosulfonylation of Unactivated Alkenes with Visible-Light Organic Photocatalysis

<strong>Origin of the data: </strong>Experimental spectroscopic measurements<br> <strong>Data Type: </strong>experimental measurements, open access supporting information The data are in CSV, DSW and FBSW format. Supporting information are supplied in PDF format. Data <strong>generated </strong>by instruments: Varian Cary 5E-UV-Vis-NIR spectrophotometer for UV-Vis measurements,<br> Varian Cary Eclipse fluorescence spectrophotomer for fluorescence quenching measurements. <strong>Analytical and procedural information: </strong>Stern-Volmer fluorescence quenching experiments, UV-Vis measurements and Fluorescent Quantum Yield determination via ferrioxalate actinometry. <strong>Definition of variables: </strong>Wavelength, Absorbance, Concentration<br> <strong>Units of measurement: </strong>nanometers (nm), moles-per-litre (mol/l) <strong>Abbreviations: </strong><br> File names and data headers use the following abbreviations: <strong>FQY </strong>refers to Fluorescence Quantum Yield determination experiments <strong>Light </strong>refers to irradiated samples in the actinometry experiment, as detailed in the procedure in the supporting information. <strong>Dark </strong>refers to non-irradiated samples in the actinometry experiment, as detailed in the procedure in the supporting information. <strong>SVQuench </strong>refers to Stern-Volmer quenching experiments <strong>RAxx </strong>refer to measurements related to allylbenzene. <strong>Xx </strong>is the amount of quencher in mol/l (05 should be intended as 0.5 mol/l and so on). <strong>RTxx </strong>refer to measurements related to <em>S</em>-(4-methylphenyl) 4-methylbenzenethiosulfonate. <strong>Xx </strong>is the amount of quencher in mol/l as above. <strong>RExx </strong>refer to measurements related to 1,2-dimethoxy-4-(prop-2-en-1-yl)benzene. <strong>Xx </strong>is the amount of quencher in mol/l as above. <strong>RSxx </strong>refer to measurements related to styrene. <strong>Xx </strong>is the amount of quencher in mol/l. <strong>RTFxx </strong>refer to measurements related to <em>S</em>-(4-fluorophenyl) 4-fluorobenzenethiosulfonate. <strong>Xx </strong>is the amount of quencher in mol/l as above. <strong>MesAcrMe Xx </strong>refers to data related to catalyst 9-mesityl-10-methylacridinium. <strong>Xx </strong>is the amount of catalyst in mol/l as above. <strong>DMC </strong>for measurements employing dimethylcarbonate as solvent. <strong>ACN </strong>for measurements employing acetonitrile as solvent.