Oxidative Coupling of Imino, Amide Platinum(II) Complexes Yields Highly Conjugated Blue Dimers
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https://figshare.com/articles/dataset/Oxidative_Coupling_of_Imino_Amide_Platinum_II_Complexes_Yields_Highly_Conjugated_Blue_Dimers/4517138
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资源简介:
Platinum(II)
olefin compounds [PtMe(N,N′-imino,
amide)(η2-olefin)] have
been found to dimerize spontaneously in solution, yielding dinuclear
complexes through an oxidative coupling. The extended conjugation
within the molecules produces an intense blue color, and the properties
of the compounds have been investigated through NMR spectroscopy,
optical measurements, and
theoretical calculations. The solid-state structure of a representative
compound has been solved.
创建时间:
2017-01-04



