An Unprecedented M–O Cluster Constructed from Nanosized {[C<sub>5</sub>NH<sub>5</sub>]<sub>9</sub>[H<sub>31</sub>Mo<sup>V</sup><sub>12</sub>O<sub>24</sub>Co<sup>II</sup><sub>12</sub>(PO<sub>4</sub>)<sub>23</sub>(H<sub>2</sub>O)<sub>4</sub>]}<sup>2–</sup> Anions Exhibiting Interesting Nonlinear-Optical Properties
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数据链接：
https://figshare.com/articles/dataset/An_Unprecedented_M_O_Cluster_Constructed_from_Nanosized_C_sub_5_sub_NH_sub_5_sub_sub_9_sub_H_sub_31_sub_Mo_sup_V_sup_sub_12_sub_O_sub_24_sub_Co_sup_II_sup_sub_12_sub_PO_sub_4_sub_sub_23_sub_H_sub_2_sub_O_sub_4_sub_sup_2_sup_Anions_Exhibiting_Interesting_N/4220505数据链接链接失效反馈
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资源简介：
A novel high-nuclear nanosized cluster modified by conjugated organic ligands (pyridine and imidazole), [C5NH5]8[C3H5N2]2{[C5NH5]9[H31Mo12O24Co12(PO4)23(H2O)4]}·12H2O (1), has been successfully isolated under hydrothermal conditions and structurally characterized. Compound 1 consists of 12 CoII and 12 MoV ions linked by 23 {PO4} groups, exhibiting unprecedented nanosized ship-shaped clusters. The magnetic measurements reveal that compound 1 exhibits dominant antiferromagnetic interactions. Additionally, pyridine and imidazole ligands enhance the delocalized electron effects of clusters, and the third-order nonlinear-optical response of compound 1 is excellent.
创建时间：
2016-11-15
