A Route to Metal–Organic Frameworks through Framework Templating
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A microporous metal–organic framework (MOF), PCN-922 [Cu4(ETTB)], containing a dendritic octatopic organic linker and a Cu2-paddlewheel structural motif, has been synthesized by using a Zn2-paddlewheel-based MOF as a template to prearrange the linkers for the Cu2-based MOF target. PCN-922 shows permanent porosity and excellent gas adsorption capacity.
创建时间:
2016-02-20



