Self-Assembly of Nanoscale Supramolecular Truncated Tetrahedra
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https://figshare.com/articles/dataset/Self_Assembly_of_Nanoscale_Supramolecular_Truncated_Tetrahedra/3282700
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资源简介：
Two nanoscale truncated tetrahedra were synthesized via
Pt(II)-mediated self-assembly. The first resulted from the
reaction of 3 equiv of cis-Pt(PMe3)2(OTf)2 and 2 equiv of
1,3,5-tris(4-pyridylethynyl)benzene, giving a truncated tetrahedron with a diameter of approximately 25 Å. The second,
analogous structure was obtained by the self-assembly of
cis-Pt(PMe3)2(OTf)2 and 1,3,5-tris(4-pyridyl-trans-ethenyl)benzene. These two truncated tetrahedra were crystallized
after partially exchanging the counterion to cobalticarborane
for the X-ray structural analysis.
创建时间：
2016-05-06
