Palladium/l‑Proline-Catalyzed Enantioselective α‑Arylative Desymmetrization of Cyclohexanones
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https://figshare.com/articles/dataset/Palladium_l_Proline_Catalyzed_Enantioselective_Arylative_Desymmetrization_of_Cyclohexanones/3181429
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A highly enantioselective palladium/l-proline-catalyzed α-arylative desymmetrization of cyclohexanones was developed. The new strategy for α-arylation reaction led to a series of optically active morphan derivatives bearing α-carbonyl tertiary stereocenters in good yields with excellent enantioselectivities (up to 99% ee).
创建时间:
2016-04-21



