Multicomponent diffusion in polymeric liquids.
收藏PubMed Central1996-07-23 更新2026-05-02 收录
下载链接:
https://pmc.ncbi.nlm.nih.gov/articles/PMC38762/
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资源简介:
It is shown how the phase-space kinetic theory of polymeric liquid mixtures leads to a set of extended Maxwell-Stefan equations describing multicomponent diffusion. This expression reduces to standard results for dilute solutions and for undiluted polymers. The polymer molecules are modeled as flexible bead-spring structures. To obtain the Maxwell-Stefan equations, the usual expression for the hydrodynamic drag force on a bead, used in previous kinetic theories, must be replaced by a new expression that accounts explicitly for bead-bead interactions between different molecules.
提供机构:
National Academy of Sciences
创建时间:
1996-07-23



