Synthesis of the Branched Tetrasaccharide Fragment of Saccharomicin A
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https://figshare.com/articles/dataset/Synthesis_of_the_Branched_Tetrasaccharide_Fragment_of_Saccharomicin_A/21858250
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A synthesis of the branched tetrasaccharide fragment of saccharomicin A using 1-OTBS donors to stereoselectively synthesize both α- and β-linked disaccharides is reported. The disaccharides were united using BSP/Tf2O to afford the tetrasaccharide fragment as a single α-anomer in 72% yield. This branched tetrasaccharide fragment can be used as donor and acceptor species to synthesize larger fragments of saccharomicin A.
创建时间:
2023-01-10



